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doi:10.22028/D291-45568 | Title: | Stereoselective Syntheses of Highly Substituted Tetrahydrofurans based on Matteson Homologations |
| Author(s): | Tost, Markus Kazmaier, Uli |
| Language: | English |
| Title: | Chemistry |
| Volume: | 31 |
| Issue: | 22 |
| Publisher/Platform: | Wiley |
| Year of Publication: | 2025 |
| Free key words: | Cycloetherifications Matteson homologations Natural products Polyketides Tetrahydrofurans |
| DDC notations: | 500 Science |
| Publikation type: | Journal Article |
| Abstract: | Deprotonated trimethylsilylethanol is an excellent nucleophile for Matteson homologations. It can be introduced in high yields and the products are stable under the usual basic reaction conditions. After two further homologation steps, the protective group is automatically cleaved off via a six-membered ring O-B coordination, providing highly substituted tetrahydrofurans. |
| DOI of the first publication: | 10.1002/chem.202500560 |
| URL of the first publication: | https://doi.org/10.1002/chem.202500560 |
| Link to this record: | urn:nbn:de:bsz:291--ds-455681 hdl:20.500.11880/40093 http://dx.doi.org/10.22028/D291-45568 |
| ISSN: | 1521-3765 0947-6539 |
| Date of registration: | 6-Jun-2025 |
| Description of the related object: | Supporting Information |
| Related object: | https://chemistry-europe.onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fchem.202500560&file=chem202500560-sup-0001-misc_information.pdf |
| Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
| Department: | NT - Chemie |
| Professorship: | NT - Prof. Dr. Uli Kazmaier |
| Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
Files for this record:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Chemistry A European J - 2025 - Tost - Stereoselective Syntheses of Highly Substituted Tetrahydrofurans based on Matteson.pdf | 2,56 MB | Adobe PDF | View/Open |
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